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teak wonder dressing sealer material safety data sheet according to 1907/2006/ce art 31 regulations 1 product and company identification teak wonder dressing sealer ­ sealer for teak for leisure crafts cod.iss twds product identification company identification barka s.r.l strada padana superiore 256/266 20090 vimodrone mi ­ italy tel +39.02.27.40.80.33 fax +39.02.25.04.072 ­ info@barka.it www.barka.it emergency telephone centro antiveleni ­ ospedale niguarda +390266101029 2 hazards identification material or preparation classification the preparation is classified hazardous according to criteria of 67/548/eec and 1999/45/ec and subsequent modifications and adjustments therefore the preparation requires a material safety data sheet conform to provisions of 1907/2006/ce art 31 regulations and subsequent modifications possible additional informations concerning health and/or environmental risks are indicated in sections 11 and 12 of this data sheet health risks harmful ­ inflammable may cause lung damage if swallowed hazards symbols xn harmful r phrases 10-65 hazards identification the product due to its physical and chemical characteristics must be considered inflammable inflammation point equal or higher than 21°c and minor or equal to 55°c 3 composition/information on ingredients xn xn r10 r65 r10 r65 1-10 gliceroftalic resin 90-100 naphtha petroleum medium aliph index 649-405-00-x the complete text of risk phrases r is reported in section 16 of this data sheet 4 eyes skin inhalation ingestion first-aid measures h4 note rinse immediately with plenty of water for at least 15 minutes get immediate medical attention wash immediately with plenty of water remove contaminated clothing if irritation persists get medical attention wash contaminated clothing before reuse move victim to fresh air if breathing is difficult get immediate medical attention get immediate medical attention induce vomiting on medical advice only never give anything by mouth to an unconscious victim and without medical authorization 5 fire-fighting measures general information use water jet to cool containers in order to avoid product decomposition and generation of substances potentially harmful for the health sealed containers exposed to fire heat may generate overpressure with explosion danger always wear full protective fireproof equipment recover extinction waters that must not be disposed of in sewerage contaminated water that has been used for extinguishing fire and rests of the fire must be disposed of pursuant to applicable provisions extinguishing media the extinguishing media are the traditional ones co2 foam dry chemicals for flammable liquids nebulized water do not use water jets water is not effective to extinguish fire but may be used to keep fire-exposed containers cool in order to prevent explosions risks due to exposure avoid inhalation of combustion results carbon oxides toxic pyrolysis products etc in case of fire equipment protective helmet with visor fireproof clothing fireproof jacket and trousers with bands around arms legs and waist intervention gloves fire fighting anti cut and dielectric self-contained breathing apparatus auto protector 1 rev 1-14/09/10

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6 accidental release measures remove all sources of ignition cigarettes flames sparks etc or of heat in the accidental release area in case of powder or vapours dispersed in the air adopt a respiratory protection stop the accidental release if there is no danger do not manipulate damaged containers or the leaked product without previously wearing the appropriate protective equipment for information concerning environmental and health risks respiratory protection ventilation and personal protection measures see the other sections of this data sheet avoid that the product sinks in sanitation surface water ground water and confined areas absorb the leaked product with inert material sand vermiculite diatomaceous soil kieselguhr etc raise most of the resulting material and deposit it in containers for disposal if there are no contraindications remove residue with water jets ensure adequate ventilation of the area affected by the accidental release contaminated material must be disposed of pursuant to point 13 hereafter personal precautions environmental precautions methods for cleaning 7 handling and storage store in fresh and ventilated area keep containers closed when not used do not smoke during manipulation keep away from heat sparks flames and other sources of ignition 8 exposure controls/personal protection as the use of appropriate technical measures should always have priority over personal protection equipment ensure good ventilation of the workplace through effective local exhaust or discharge of polluted air if these steps do not maintain the concentration below the exposure limit values in the workplace adopt a suitable protection to respiratory during use of the product see hazard label for details for the choice of personal protection equipment ask advice of own chemicals suppliers personal protection equipment must comply with standards below hands protection protect hand with work gloves of category i ref dir 89/686/cee and provision en 374 as in latex pvc or equivalent for the final choice of material for work gloves you should consider degradation break-up time and permeation in case of prepared products the resistance of work gloves must be verified before use because not predictable gloves have a wear time depending on the exposure duration eyes protection recommended sealed goggles provision en 166 skin protection wear work clothing with long sleeves and safety footwear for professional use of category i ref dir 89/686/cee and provision en 344 wash with water and soap after removing work clothes respiratory protection in case of exceeding the daily exposure limit values of one or more of the preparation substances in the workplace or of a fraction determined by the service of prevention and corporate security wear a mask with an a filter or an universal filter which class 1 2 or 3 shall be chosen according to the concentration limit of use ref provision en 141 the use of respiratory protection measures as masks with cartridge for organic vapours and dust/mist is necessary in absence of technical measures for limiting worker exposure the protection provided by masks is however limited in the case where the substance in question is odourless or its olfactory threshold is higher than the relative exposure limit and in case of emergency or when exposure levels are unknown or the concentration of oxygen in the workplace is less than 17 by volume wear a compressed air breathing apparatus open circuit ref provision en 137or respirator air hose with full face mask half mask or mouthpiece ref provision en 138 9 physical and chemical properties appearance liquid with background body color brown odor mineral spirits solubility not miscible vapor density 2,1 boiling point 145° c flashpoint 35° c lower explosive limit 1 v/v higher explosive limit 2 v/v auto ignition temperature >200 c° specific gravity 0,791 kg/l dry residual 6,06 voc dir 1999/13/ce 93,94 voc volatile carbon 79,89 10 stability and reactivity the product is stable under normal conditions of usage and storage due to thermal decomposition or in case of fire potentially harmful vapours may be produced rev 1-14/09/10 2

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11 toxicological information there are no known incidents of damage to health caused by exposure to the product in any case it is recommended to operate in compliance with good industrial hygiene standards the product in particularly susceptible subjects may cause minor health effects on exposure to inhalation and/or or skin absorption and/or eye contact and/or ingestion 12 ecological information utilize pursuant to good working standards avoiding environmental dispersions inform the authorities if the product has reached running waters or drainages or if it has contaminated soil or vegetation the dearomatized mineral turpentine tends to be divided almost exclusively in the air where it photodegrades the small portion that remains in the water tends to sink to the bottom and biodegrade so there is no bioaccumulation in fish in soil the substance is absorbed and therefore cannot reach any groundwater 13 disposal considerations reutilize if possible product residues are considered special hazardous waste the danger of waste containing this product should be evaluated according to applicable regulations disposal should be entrusted to an authorized waste management in compliance with national and local regulations contaminated packaging contaminated packaging must be reused or disposed of in compliance with national regulations on waste disposal 14 transport information the product must be transported by vehicles authorized to transport dangerous goods pursuant to regulations of a.d.r agreement current edition the product must be transported in original packaging and in any case in packaging made of materials resistant to their content and not likely to generate with this dangerous reactions workers loading and unloading the dangerous must have received appropriate training on the risks associated with the product and the actions that must be taken in case of emergencies un 1263 paint and paint related material class adr 3 pg iii exemptions lq7-pp1 partials cat 3 1000 kg supplemental prescriptions s2 road or rail transport adr/rid class packing group label n kemler limited quantity tunnel restriction code technical name special provision sea transport 3 un 1263 iii 3 30 lq07 d/e paint and paint related material 640e imo class packing group label ems marine pollutant proper shipping name air transport 3 un 1263 iii 3 f-e s-e no paint or paint related material rev 1-14/09/10 3

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iata packing group label cargo packaging instructions pass packaging instructions special provisions proper shipping name 15 3 iii 3 310 un 1263 maximum quantity 220 l 309 maximum quantities 60 l a3 a72 paint or paint related material regulatory information ec harmful labelling according to dir 67/548/cee and 1999/45/ce and subsequent modifications and adjustments not subject to dir 2004/42/ce and subsequent modifications because for leisure crafts only symbol of danger to health xn harmful ­ contains turpentine dearomatised security phrases s 2 keep locked up and out of the reach of children 23 do not breath vapours 43 in case of fire use foam powder or co2 do not use water 51 use in well ventilated areas only 16 other information risks phrases as per section 3 10 inflammable 65 harmful may cause lung damage if swallowed general bibliography 1 d.l.260 28/7/2004 2 dir 1999/45/ce and subsequent modifications 3 dir 67/548/cee and subsequent modifications and adjustments xxix technical adjustment 4 dir 91/155/cee and subsequent modifications 5 the merck index ed 10 6 handling chemical safety 7 niosh registry of toxic effects of chemical substances 8 inrs fiche toxicologique 9 patty industrial hygiene and toxicology 10 n.i saxdangerous properties of industrial materials-7 ed 1989 11 reg ce 1907/2006 reach annotations for the user the information contained herein is believed to be factual at the date this material safety data sheet was last revised the user should review any recommendation in the specific context of the intended use to determine whether they are appropriate nothing contained herein is to be taken as a warranty or representation for which the producer and/or importer and/or reseller is legally liable since the use of the product is under the exclusive control of the user the user is responsible for the compliance with all applicable safety and health legal provisions no company s liability for improper use rev 1-14/09/10 4

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